Mixed-Plastics Recycling – Nafion, the Core Innovation in Rechargeable Solid Air Batteries 25-09-2023

Mixed-Plastics Recycling

Petrochemicals r-PET – Nafion, the Core Innovation in Rechargeable Solid Air Batteries

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Mixed-Plastics Recycling

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Crude Oil Prices Trend by Polyestertime

Crude Oil Prices Trend by Polyestertime

The UN’s chief of environmental affairs has issued a stark warning regarding the escalating production and pollution caused by plastic

She asserts that simply relying on plastic recycling is insufficient to address this crisis, urging a comprehensive reevaluation of our plastic consumption patterns.

Inger Andersen, the director of the UN Environment Program, emphasized during an interview at the General Assembly in New York that with plastic production soaring globally and pollution worsening, the status quo cannot be maintained. She underscored the need for a collective reimagining of how we utilize plastic materials.

Two weeks following the release of the initial draft of an impending international treaty on plastic pollution, anticipated to be finalized by the end of 2024, Andersen shared insights into the diverse ambitions of the 175 participating nations.

These ambitions range from advocating for a reduction in raw polymer production to emphasizing reuse and recycling.  Mixed-Plastics Recycling

Andersen’s approach starts with eliminating as many single-use plastics as possible, especially those that serve no necessary purpose, such as items wrapped in plastic that are naturally encased, like oranges or bananas. She also suggested reevaluating the very nature of products, questioning whether they need to be in liquid form and exploring alternatives like powders, compressed forms, or concentrates. For instance, she mentioned her habit of checking the soap aisle in supermarkets for solid alternatives.

Furthermore, Andersen stressed the importance of reducing the overall supply of new raw polymer, an option outlined in the draft treaty text. She pointed out that while recycling efforts are essential, plastic usage continues to rise. Over the past two decades, annual plastic production has more than doubled, reaching 460 million tons, and this figure could triple by 2060 if no significant changes occur. Currently, only nine percent of plastic is recycled, leading to plastic waste contaminating oceans, wildlife, and even human biological systems through microplastic pollution. Mixed-Plastics Recycling

Andersen emphasized that relying solely on recycling will not suffice in addressing this crisis. She expressed that if the inflow of new raw polymer into the economy remains unchecked, the problem of plastic pollution in oceans will persist. She underscored the critical importance of ocean health for humanity’s future.

The future treaty on plastic pollution is expected to complement global initiatives aimed at protecting oceans, including the recent historic treaty covering the high seas, which was signed by around 70 nations. Andersen hailed this development as a vital step in safeguarding a crucial portion of our shared heritage—the oceans.

Mixed-Plastics Recycling

New Chemical Process Offers Hope for Mixed-Plastics Recycling

A molecular additive allows different kinds of plastic to be recycled together

Soda bottles, sour cream containers and disposable cutlery—these plastics (and many others) typically arrive at recycling plants mixed together in the same bin. But because they are made of different molecular building blocks, called monomers, they must be sorted into different streams before they can be melted to make new products.

“Until about a year ago, everybody thought the only thing you could do is take a plastic, break it back down to a monomer and then re-form it,” says Sanat Kumar, a chemical engineer at Columbia University. “Now we’ve come up with a different way of doing it.” His team has developed a process that allows different kinds of plastic to be recycled together. Their findings, reported recently in Nature, could give new life to many items that end up in landfills. Mixed-Plastics Recycling

A disturbingly small portion of our plastic waste is recycled, and production of new plastic—made from fossil fuels—continues to increase. The worsening situation has prompted scientists to seek new solutions to old recycling problems, including the difficulty of recycling mixed plastics. But they have faced a fundamental chemical hurdle: when different plastics are melted together, their various monomers tend to separate from one another like oil and water.

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Mixed-Plastics Recycling

Credit: Thomas Fuchs

Introducing the Innolith I-State: A Swiss Battery Revolutionizing Electric Vehicle Autonomy

Innolith, a Swiss pioneer in battery production, has unveiled a groundbreaking innovation in the world of electric vehicles—an extraordinary cell that not only reduces manufacturing costs but also extends the range of electric vehicles to well over 1,000 kilometers. Named the “I-State,” this battery employs a novel chemical composition, complemented by a non-flammable liquid electrolyte, which collectively enables it to operate at higher voltages, surpassing the conventional limit of 4.2 volts and reaching up to 5 volts.

Key Features:

  • Exceptional Energy Density: The Innolith I-State boasts an impressive volumetric density of 825 Wh/l.
  • Versatility in Temperature: This battery is engineered to function reliably in a broad temperature range, spanning from -40 degrees to +60 degrees Celsius.

Konstantin Solodovnikov, the CEO of Innolith, highlighted the pressing need for improved batteries to accelerate the transition to a greener economy. He pointed out that conventional lithium-ion batteries, though dependable for decades, have revealed limitations that must be addressed in the future. The I-State battery, with its enhanced performance, reduced costs, and environmental sustainability, emerges as a game-changer in this context. Mixed-Plastics Recycling

Solodovnikov emphasized that this innovative technology will play a pivotal role in supporting electric vehicles during the global shift towards eco-friendliness and renewable energy. Furthermore, Innolith is actively researching advancements in energy density and performance for future iterations of this technology.

Collaborative Efforts: Innolith’s I-State batteries are poised to enter the market through partnerships with leading automotive manufacturers and industry stakeholders. Additional details about these partnerships will be disclosed in due course. Excitingly, discussions are underway to license production, with the potential to yield an impressive annual output of 100 MWh of I-State batteries. Five companies have already expressed interest, and Innolith has entered into a letter of intent with a prominent enterprise, though the identity of this partner remains confidential for now. Mixed-Plastics Recycling

Introducing the Innolith I-State: A Swiss Battery Revolutionizing Electric Vehicle Autonomy

Elix Polymers Unveils E-Loop Sustainable Materials at Fakuma 2023

Elix Polymers, a leading global supplier of specialty ABS materials headquartered in Spain, is set to unveil its latest eco-friendly E-Loop product line at the upcoming Fakuma 2023 exhibition in Friedrichshafen, Germany, scheduled for October 17 to 21. The company has consolidated its efforts in the circular economy realm under the E-Loop brand, encompassing two key initiatives from Elix Sustainable Portfolio Solutions: Circular Plastics and Responsible Innovation. Elix will use the Fakuma platform to present its most impactful circular solutions and innovations, carrying the banner of “Let’s close the loop” at booth 5003 in hall B5. Mixed-Plastics Recycling

Visitors to the Elix stand can expect to see an array of products featuring mechanically recycled content, including E-Loop H801 MR, E-Loop Ultra 4105 MR, and E-Loop PC/ABS 5120 MR. These offerings maintain properties akin to their conventional prime counterparts while achieving a remarkable 29% reduction in CO2 emissions. Notably, these materials have garnered approval from various premium automotive Original Equipment Manufacturers (OEMs) and have received validation from key tiers, with applications spanning the demanding landscape of both interior and exterior automotive components.

Among the highlights of the E-Loop range are the E-Loop CR products, crafted from sustainable certified raw materials that encompass circular and bio-based feedstocks. These products hold certification under ISCC+ (International Sustainability and Carbon Certification), with a meticulous mass balance model ensuring complete traceability and transparency across the supply chain. The flexibility of E-Loop CR products lies in the diverse sourcing options for the three primary monomers: fossil-fuel-based feedstocks, chemically recycled post-consumer waste, and bio-based feedstocks. Depending on the specific monomer blend employed, emissions reductions of up to 60% in comparison to prime-grade materials can be achieved. Mixed-Plastics Recycling

A testament to Elix Polymers’ commitment to sustainability, the company has received UL yellow cards for its E-Loop product lineup featuring certified raw materials, responding to the demands of customers within the electrical and electronics, as well as consumer goods sectors. Plastic pollution Petrochemicals

Salt Water-Degradable Plastics To Help Oceans

“Researchers at the University of Queensland are developing a groundbreaking solution to combat marine pollution: saltwater-degradable plastics. Dr. Ruirui Qiao, affiliated with UQ’s Australian Institute for Bioengineering and Nanotechnology, is spearheading the development of an affordable, biodegradable plastic that disintegrates in seawater, aiming to mitigate the proliferation of persistent plastic waste in our oceans.

According to Dr. Qiao, our oceans are increasingly contaminated by long-lasting plastic items such as containers, bags, and microplastics, posing a significant threat to marine ecosystems and the countless seabirds and mammals that rely on them. While awareness of this issue has grown in recent years, the scale of plastic waste entering the water necessitates innovative solutions. Dr. Qiao believes that plastic degradation technologies hold promise as part of the solution. Mixed-Plastics Recycling

Collaborating with fellow researchers, including Professor Tom Davis and Professors Xuan Pang and Xuesi Chen from the Changchun Institute of Applied Chemistry, Dr. Qiao’s team is utilizing cutting-edge 3D-printing techniques developed by her research group at AIBN and polymeric materials from the Chinese Academy of Sciences to create a range of customizable, high-value seawater-degradable plastics.

This collaborative effort has received $125,000 in funding from the Queensland-Chinese Academy of Sciences Collaborative Science Fund to expedite the project’s progress over the next two years. One of the techniques they are employing, known as ring-opening polymerization, enables precise control over the mechanical properties and form of the plastics while imbuing them with a low-toxic polyester “backbone.” As a result, these plastics can break down into a molecular state when exposed to marine environments.

The ultimate goal is to commercialize a new line of products in both Australia and China within five years, effectively replacing conventional plastics and capitalizing on a burgeoning biodegradable market projected to exceed $9.5 billion by that time. Dr. Qiao emphasizes that seawater-degradable polymer plastics will play a vital role in reducing plastic debris in the world’s oceans, enhancing the well-being of ecosystems and the quality of life for communities globally. Mixed-Plastics Recycling

In addition to their innovative work, the research team is fostering collaboration between research groups in Queensland and China to further advance their expertise in polymer science and additive manufacturing.”

Salt Water-Degradable Plastics To Help Oceans

UN Environment Chief Warns Recycling Alone Isn’t Sufficient

Over the past two decades, annual plastic production has surged, exceeding 460 million tons. With the global plastic production spiraling upward and causing escalating pollution, the UN’s environment chief has issued a stark warning that merely relying on recycling won’t extricate humanity from this crisis. Instead, she calls for a comprehensive reevaluation of our plastic consumption habits.

In an interview conducted on September 21st, during the General Assembly in New York, Inger Andersen, Director of the UN Environment Program, emphasized that the prevailing status quo is no longer a viable option. She pointed out that there are various approaches to find solutions to this predicament, but the urgency for change is evident to all.

Andersen’s remarks come on the heels of the publication of the initial draft of an impending international treaty on plastic pollution, set to be finalized by the conclusion of 2024. This treaty represents the diverse aspirations of 175 participating nations, notably highlighting the divergence between those advocating for reduced polymer production and those championing reuse and recycling. Mixed-Plastics Recycling

Initially, Andersen stressed the objective of eliminating as many single-use plastics as possible, targeting items that are evidently unnecessary, such as products wrapped in plastic that serve little purpose, or even those encased in natural packaging, like oranges or bananas. Subsequently, she highlighted the need to reconsider the very nature of products themselves. Questions about the necessity of products being in liquid form, and the potential for them to be reformulated as powders, compressed forms, or concentrates, must be seriously entertained. Andersen noted her personal habit of going straight to the soap aisle in supermarkets to check for solid alternatives.

UN Environment Chief Warns Recycling Alone Isn't Sufficient

Chemical recycling innovation – BASF Secures Long-Term Access to Bio-Based 1,4-Butanediol (BDO) through QIRA 23-09-2023

Mixed-Plastics Recycling

Petrochemicals r-PET – Nafion, the Core Innovation in Rechargeable Solid Air Batteries 25-09-2023

Petrochemicals r-PET

Petrochemicals r-PET

  • Polymers : PET – r-PET – Filament grade semidull chips -Filament grade bright chips – Ny6 – Ny66 – PP
  • Feedstocks : PX – PTA – MEG – CPL – Adipic Acid – Benzene – ACN – Ethylene – Phenol – Naphtha
  • Textile : Polyester POY – DTY – FDY – PSF – Recycled Polyester POY – Nylon POY – DTY – FDY Spandex 20-30-40 -Viscose Staple Fiber VSF  Acrylic Staple Fiber Petrochemicals Polymers

Petrochemicals r-PET

Polyestertime
ITEM 18/09/2023 25/09/2023 +/-
Bottle grade PET chips domestic market 7,300 yuan/ton 7,200 yuan/ton -100
Bottle grade PET chips export market 915 $/ton 905 $/ton -10
Filament grade Semidull chips domestic market 7,300 yuan/ton 7,150 yuan/ton -150
Filament grade Bright chips domestic market 7,340 yuan/ton 7,240 yuan/ton -100
Pure Terephthalic Acid PTA domestic market 6,340 yuan/ton 6,215 yuan/ton -125
Pure Terephthalic Acid PTA export market 800 $/ton 810 $/ton +10
Monoethyleneglycol MEG domestic market 4,275 yuan/ton 4,130 yuan/ton -145
Monoethyleneglycol MEG export market 494 $/ton 480 $/ton -14
Paraxylene PX FOB  Taiwan market

Petrochemicals r-PET

1,160 $/ton 1,133 $/ton
-27
Paraxylene PX FOB  Korea market 1,137 $/ton 1,110 $/ton -27
Paraxylene PX FOB EU market 1,200 $/ton 1,250 $/ton +50
Polyester filament POY 150D/48F domestic market 8,200 yuan/ton 8,100 yuan/ton
-100
Recycled Polyester filament POY  domestic market 7,750 yuan/ton 7,550 yuan/ton -200
Polyester filament DTY 150D/48 F domestic market 9,600 yuan/ton 9,450 yuan/ton -150
Polyester filament FDY 68D24F

Petrochemicals r-PET

9,350 yuan/ton 9,300 yuan/ton -50
Polyester filament FDY 150D/96F domestic market 8,750 yuan/ton 8,700 yuan/ton -50
Polyester staple fiber 1.4D 38mm domestic market 7,850 yuan/ton 7,770 yuan/ton -80
Caprolactam CPL domestic market 14,280 yuan/ton 13,375 yuan/ton
-905
Caprolactam CPL overseas  market 1,600 $/ton 1,600 $/ton
Nylon 6 chips overseas  market 1,790 $/ton 1,830 $/ton +40
Nylon 6 chips conventional spinning domestic  market 15,000 yuan/ton 14,450 yuan/ton -550
Nylon 6 chips  high speed spinning domestic  market

Petrochemicals r-PET

15,350 yuan/ton 15,100 yuan/ton -250
Nylon 6.6 chips domestic  market 19,000 yuan/ton 19,500 yuan/ton +500
Nylon6 Filament POY 86D/24F domestic  market 17,450 yuan/ton 17,200 yuan/ton -250
Nylon6 Filament DTY 70D/24F domestic  market 19,600 yuan/ton 19,400 yuan/ton- -200
Nylon6 Filament FDY  70D/24F  18,350 yuan/ton 18,150 yuan/ton -200
Spandex 20D  domestic  market

Petrochemicals r-PET

36,500 yuan/ton 36,500 yuan/ton
Spandex 30D  domestic  market 35,000 yuan/ton 35,000 yuan/ton
Spandex 40D  domestic  market  32,200 yuan/ton 32,200 yuan/ton
Adipic Acid domestic market 10,050 yuan/ton 9,900 yuan/ton -150
Benzene domestic market

Petrochemicals r-PET

8,540 yuan/ton 8,075 yuan/ton -465
Benzene overseas  market 1,023 $/ton 980 $/ton -43
Ethylene South East market 865 $/ton 870 $/ton +5
Ethylene NWE market 788 $/ton 783 $/ton -5
Acrylonitrile ACN  domestic market

Petrochemicals r-PET

9,500 yuan/ton 9,700 yuan/ton +200
Acrylonitrile ACN  overseas market 1,200 $/ton 1,200 $/ton
Acrylic staple fiber ASF  domestic market 14,100 yuan/ton 14,100 yuan/ton
Viscose Staple Fiber VSF  domestic market 13,250 yuan/ton 13,400 yuan/ton +150
PP Powder domestic market

Petrochemicals r-PET

7,700 yuan/ton 7,550 yuan/ton -150
Naphtha overseas market  713 $/ton 719 $/ton +6
Phenol domestic market 9,795 yuan/ton 9,407 yuan/ton -388

 

r-PET high end eco-friendly chips =7,800 yuan/ton 7,800 yuan/ton   –

Petrochemicals r-PET

Nafion, the Core Innovation in Rechargeable Solid Air Batteries

The development of Nafion-based air batteries by Japanese researchers stands as a groundbreaking achievement in the realm of renewable and sustainable energy. These batteries have successfully sidestepped the use of heavy metals and liquid electrolytes, resulting in a marked reduction in their environmental footprint. At the heart of this revolutionary transformation lies Nafion, a proton-conducting polymer that not only excels in performance but also extends the lifespan of these batteries. Despite their initial lower discharge capacities, diligent optimization efforts have yielded promising outcomes. This advancement represents a crucial milestone on the path towards a cleaner and more sustainable energy future.

Transitioning towards a sustainable energy future necessitates the exploration of renewable energy sources beyond photovoltaics. Petrochemicals r-PET

While photovoltaics has undeniably demonstrated its worth as a clean energy source, its widespread adoption poses environmental challenges related to solar panel production and disposal.

The quest for novel renewable energy sources becomes imperative in meeting the ever-growing energy demands of contemporary conveniences without further harm to the environment. Batteries play a pivotal role in facilitating this transition towards a more sustainable energy landscape.

The surging demand for electronic devices and electric vehicles underscores the urgency for more efficient and environmentally friendly batteries. In Japan, a team of researchers has taken a revolutionary stride by introducing an entirely solid air battery founded on the remarkable properties of Nafion material.

This innovation has the potential not only to reshape the battery industry but also to revolutionize the entire energy sector. Petrochemicals r-PET

Solid Air Batteries: An Environmentally Friendly Solution

The urgency to combat climate change and reduce carbon emissions has galvanized extensive research into eco-friendly energy solutions. Batteries, as a fundamental component of these solutions, have assumed a central role in extensive studies and groundbreaking innovations. The primary challenge lies in developing batteries that are not only more efficient and durable but also environmentally sustainable.

Air batteries emerge as a promising solution to this challenge. In stark contrast to traditional batteries reliant on heavy metals, air batteries eliminate these environmentally detrimental components, resulting in a substantial reduction in their environmental footprint. However, until recently, the majority of air batteries depended on liquid electrolytes, which posed issues related to electrical resistance and fire hazards.

Nafion: A Revolutionary Polymer

Researchers from Waseda and Yamanashi Universities in Japan have chosen Nafion as the proton-conducting polymer for their innovative solid air battery. Petrochemicals r-PET

The utilization of Nafion not only obviates the need for liquid electrolytes but also ushers in enhanced performance and prolonged durability. The battery boasts an anode crafted from a chemical compound known as 2,5-hydroxy-1,4-benzoquinone, complemented by a cathode composed of the polymer 2-hydroxy-1,4-benzoquinone-3,6-methylene. This amalgamation, alongside Nafion serving as the electrolyte, has yielded a solid air battery with extraordinary performance capabilities.

Promising Performance and the Road to Sustainability

While the initial discharge capacity of semiconductor air batteries fell short of other technologies, meticulous adjustments in composition have led to substantial enhancements. The accumulator’s coulombic efficiency reached 84% at 4°C, and through successive cycles and refinements, the discharge capacity surged to 78%. This progress signifies a noteworthy stride towards a sustainable energy future, where clean and sustainable energy emerges as a tangible and compelling alternative to more well-established renewable sources. Petrochemicals r-PET

Nafion, the Core Innovation in Rechargeable Solid Air Batteries